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Glittering
Stones >> Synthetic Corundum
Synthetic corundum
Corundum is the crystalline form of aluminum
oxide (Al2O3) and one of the rock-forming minerals. Corundum is
obviously clear, but can have dissimilar colors when impurities
are added. Transparent specimens are used as gems,
called ruby if red, while all other colors are
known as sapphire. The word corundum
comes from the Hindu Kurland.
Corundum has a hardness of 8 on the 10 point Mohs' scale, a exact
gravity of 5.00 and a hexagonal crystal structure.
The oxygen atoms are approved in a hexagonal close packing, with
the smaller aluminum atoms occupying 2/3 of the octahedral gaps.
The coordination of the atoms is thus 6:5, compared to 4:6 for
quartz, which accounts for its greater rigidity despite the Al-O
bonds being less covalent. Its index of refraction is 1.77 - 1.79
and its birefringence is 0.008.
Due to corundum's hardness, it is frequently
used in as an abrasive in machining, from huge machines to sandpaper.
Emery is an adulterated and less abrasive variety, with a Mohs
hardness of 8.0. Diamond is harder, but much more expensive.
Properties of Synthetic Sapphire and Ruby
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| Generally properties |
Chemical composition
Crystal structure
Purity
Melting point
Softening point
Specific heat |
Al2O3
Hexagonal
99.99%
2050¡ãC
1800¡ãC
0.18 cal/g.¡ãC (25¡ãC)
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| Thermal properties & Mechanical properties |
Thermal expansion
Thermal conductivity
Density
Hardness Mohs
Knoop
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Parallel to C-axis: 6.7¡Á10-6/¡ãC
Perpendicular to C-axis: 5.0¡Á10-6/¡ãC
0.09 c
al/sec.cm.¡ãC (25¡ãC)
3.98--4.1 g/cm3
9
1800 face parallel to C-axis
2200 face perpendicular to C-axis
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